Monday, April 10, 2023

Scientists discover a new way Earth's atmosphere cleans itself at nighttime

Amazing stuff!

Remember Global Warming is a hoax and Climate Change is a religion!

"... a research team ... report that a strong electric field that exists at the surface between airborne water droplets and the surrounding air can create OH by a previously unknown mechanism.
It's a finding that stands to reshape how scientists understand how the air clears itself of things like human-emitted pollutants and greenhouse gases, which OH can react with and eliminate. ...
What they saw is that OH production rates in darkness mirror those and even exceed rates from drivers like sunlight exposure. ... "At night, when there is no photochemistry, OH is still produced and it is produced at a higher rate than would otherwise happen." ..."

From the significance and abstract:
"Significance
Recent studies suggest that reactions that do not usually occur in bulk solution can occur spontaneously in small water droplets, possibly due to the naturally formed electric field at the air–water interface. We explore the atmospheric significance of this process by demonstrating efficient spontaneous production of interfacial hydroxyl radicals (OH) from aqueous droplets under ambient conditions. This interfacial OH production does not involve precursors or catalysts, such as light or heat, and is likely the largest aqueous OH source in atmospheric droplets at nighttime. The ubiquity of aqueous aerosols and cloud droplets and their possibly strong OH-producing capability suggests that we have to rethink atmospheric multiphase oxidation chemistry.
Abstract
Hydroxyl radical (OH) is a key oxidant that triggers atmospheric oxidation chemistry in both gas and aqueous phases. The current understanding of its aqueous sources is mainly based on known bulk (photo)chemical processes, uptake from gaseous OH, or related to interfacial O3 and NO3 radical-driven chemistry. Here, we present experimental evidence that OH radicals are spontaneously produced at the air–water interface of aqueous droplets in the dark and the absence of known precursors, possibly due to the strong electric field that forms at such interfaces. The measured OH production rates in atmospherically relevant droplets are comparable to or significantly higher than those from known aqueous bulk sources, especially in the dark. As aqueous droplets are ubiquitous in the troposphere, this interfacial source of OH radicals should significantly impact atmospheric multiphase oxidation chemistry, with substantial implications on air quality, climate, and health."

Scientists discover a way Earth's atmosphere cleans itself

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