Friday, February 04, 2022

Direct evidence emerges for the existence of two forms of liquid water

The magic of water! The latest research paper on this subject was even written by one researcher alone, very unusual!

Quick reminder: We don't yet even understand water fully, but Western societies are inundated on a daily basis with the pseudoscience and pretense of knowledge of Climate Change!

"Thirty years ago, a team working at Boston University made the dramatic suggestion that there are not one but two forms of liquid water, which can interconvert at high pressure well below water’s normal freezing point.1 Researchers have been searching for this putative liquid–liquid phase transition ever since, and evidence has slowly accumulated that it really exists. New experiments now supply what seems to be a direct observation of such a transformation between liquid states of different density – not in pure water but in solutions of the sugar trehalose. ..."

From the abstract:
"Water forms two glassy waters, low-density and high-density amorphs, which undergo a reversible polyamorphic transition with the change in pressure. The two glassy waters transform into the different liquids, low-density liquid (LDL) and high-density liquid (HDL), at high temperatures. It is predicted that the two liquid waters also undergo a liquid–liquid transition (LLT). However, the reversible LLT, particularly the LDL-to-HDL transition, has not been observed directly due to rapid crystallization. Here, I prepared a glassy dilute trehalose aqueous solution (0.020 molar fraction) without segregation and measured the isothermal volume change at 0.01 to 1.00 GPa below 160 K. The polyamorphic transition and the glass-to-liquid transition for the high-density and low-density solutions were examined, and the liquid region where both LDL and HDL existed was determined. The results show that the reversible polyamorphic transition induced by the pressure change above 140 K is the LLT. That is, the transition from LDL to HDL is observed. Moreover, the pressure hysteresis of LLT suggests strongly that the LLT has a first-order nature. The direct observation of the reversible LLT in the trehalose aqueous solution has implications for understanding not only the liquid–liquid critical point hypothesis of pure water but also the relation between aqueous solution and water polyamorphism."

Direct evidence emerges for the existence of two forms of liquid water | Research | Chemistry World

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