Saturday, September 02, 2023

Scientists witness quantum superchemistry in action for the first time

Amazing stuff!

"Researchers at the University of Chicago have detected the first physical evidence of what they're calling "quantum superchemistry." During this phenomenon, particles existing in the same quantum state undergo collective accelerated reactions. While this phenomenon was predicted before, it's only now been confirmed through experiments conducted at the university's laboratory. ...
The team's experiment centered around cesium atoms, which they cooled down and manipulated into a shared quantum state. The researchers then observed the reactions that followed, which occurred as three-body interactions, with two atoms forming a molecule while the third remained single but played a role in the reaction. ..."

From the abstract:
"Chemical reactions in the quantum degenerate regime are described by the mixing of matter-wave fields. In many-body reactions involving bosonic reactants and products, such as coupled atomic and molecular Bose–Einstein condensates, quantum coherence and bosonic enhancement are key features of the reaction dynamics. However, the observation of these many-body phenomena, also known as ‘superchemistry’, has been elusive so far. Here we report the observation of coherent and collective reactive coupling between Bose-condensed atoms and molecules near a Feshbach resonance. Starting from an atomic condensate, the reaction begins with the rapid formation of molecules, followed by oscillations of their populations during the equilibration process. We observe faster oscillations in samples with higher densities, indicating bosonic enhancement. We present a quantum field model that captures the dynamics well and allows us to identify three-body recombination as the dominant reaction process. Our findings deepen our understanding of quantum many-body chemistry and offer insights into the control of chemical reactions at quantum degeneracy."

Scientists witness "quantum superchemistry" in action for the first time

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