Good news! More work is necessary!
"... This breakthrough was made possible by embedding a chromophore, a dye molecule that absorbs light and emits color, in a metal-organic framework, or MOF, a nanoporous crystalline material composed of metal ions and organic ligands. ...
Notably, chromophores can be used to excite electrons with desirable electron spins at room temperatures through a process called singlet fission. However, at room temperature causes the quantum information stored in qubits to lose quantum superposition and entanglement. As a result, it is usually only possible to achieve quantum coherence at liquid nitrogen level temperatures. ...
To suppress the molecular motion and achieve room-temperature quantum coherence, the researchers introduced a chromophore based on pentacene (polycyclic aromatic hydrocarbon consisting of five linearly fused benzene rings) in a UiO-type MOF. “The MOF in this work is a unique system that can densely accumulate chromophores. Additionally, the nanopores inside the crystal enable the chromophore to rotate, but at a very restrained angle,” ...
The MOF structure facilitated enough motion in the pentacene units to allow the electrons to transition from the triplet state to a quintet state, while also sufficiently suppressing motion at room temperature to maintain quantum coherence of the quintet multiexciton state. Upon photoexciting electrons with microwave pulses, the researchers could observe the quantum coherence of the state for over 100 nanoseconds at room temperature. ..."From the abstract:
"Singlet fission can generate an exchange-coupled quintet triplet pair state 5TT, which could lead to the realization of quantum computing and quantum sensing using entangled multiple qubits even at room temperature. However, the observation of the quantum coherence of 5TT has been limited to cryogenic temperatures, and the fundamental question is what kind of material design will enable its room-temperature quantum coherence. Here, we show that the quantum coherence of singlet fission–derived 5TT in a chromophore-integrated metal-organic framework can be over hundred nanoseconds at room temperature. The suppressed motion of the chromophores in ordered domains within the metal-organic framework leads to the enough fluctuation of the exchange interaction necessary for 5TT generation but, at the same time, does not cause severe 5TT decoherence. Furthermore, the phase and amplitude of quantum beating depend on the molecular motion, opening the way to room-temperature molecular quantum computing based on multiple quantum gate control."
Generating Stable Qubits at Room Temperature (Kyushu University) Researchers observe the quantum coherence of a quintet state with four electron spins in molecular systems for the first time at room temperature
Room-temperature quantum coherence of entangled multiexcitons in a metal-organic framework (open access)
Fig. 1. Quintet multiexciton generation and its quantum coherence in an MOF.
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