Amazing stuff!
"... A new microscopy technique has given researchers greater insight into the way that droplets and bubbles form. ...
showed that the density with which nucleation sites are populated is governed by a Poisson distribution, as expected. However, the spatial distribution – the nearest-neighbour distance – followed a Rayleigh distribution, which was unexpected given that chemical engineers have assumed for decades that this was also governed by a Poisson distribution. ..."
The formation of bubbles and droplets is at the heart of many chemical processes ... Now a new scanning electron microscopy (SEM) technique has enabled researchers to observe the nucleation process in more detail than ever before.
... used phase-enhanced environmental SEM to analyse nucleation site distribution during condensation, chemical vapor deposition and a hydrogen evolution reaction. With this technique ... could directly image electrons at a sub-micrometre scale, allowing them to build a detailed image of nucleation sites. ... showed that the density with which nucleation sites are populated is governed by a Poisson distribution, as expected. However, the spatial distribution – the nearest-neighbour distance – followed a Rayleigh distribution, which was unexpected given that chemical engineers have assumed for decades that this was also governed by a Poisson distribution. ..."
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